Spectrophotometric determination of thiourea using o-hydroxyhydroquinonephthalein and palladium (II).
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Spectrophotometric determination of glucosamine and its analogous amino sugars with o-hydroxyhydroquinonephthalein and palladium(II).
A simple and highly sensitive spectrophotometric method for the determination of glucosamine and its analogous amino sugars was established based on fading of the palladium(II)-o-hydroxyhydroquinonephthalein-hexadecyltrimethylammonium complex. In the determination of glucosamine, Beer's law is obeyed in the range of 0.02 - 0.18 microg ml(-1), with an effective molar absorptivity at 630 nm and t...
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A simple and highly sensitive spectrophotometric method for the determination of uric acid (UA) was established based on fading of the o-hydroxyhydroquinonephthalein-palladium(II)-hexadecyltrimethylammonium complex. In the determination of UA, Beer's law is obeyed in the range of 0.01-0.20 microg ml(-1), with an effective molar absorptivity at 635 nm, the relative standard deviation being 6.5 x...
متن کاملSolvent extraction, spectrophotometric determination of copper (II) from environmental samples using o-methylphenyl thiourea as a novel reagent
A simple and rapid method has been developed for solvent extraction and spectrophotometric determination of copper (II) using o-methylphenyl thiourea (OMPT) as a sensitive reagent. The basis of proposed method is formation of copper (II)-OMPT complex. Copper (II) was extracted with 0.020 mol L-1 OMPT in chloroform from aqueous solution in 0.075 mol L-1 potassium iodate. The absorbance of comple...
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Simultaneous and fractional determination of iron(II) and iron(III) was accomplished with o-hydroxyhydroquinonephthalein (QP) in the presence of poly (N-vinyl pyrrolidone). In the determination of total iron (iron(II)+iron(III)), Beer's law was obeyed in the range of 0.02-0.67 μg·ml(-1), with an effective molar absorptivity (at 570 nm) and a relative standard deviation of 1.30×10(5)·l·mol(-1)·c...
متن کاملSpectrophotometric determination of palladium(II) using a nitrogen, sulphur and oxygen donor triazine
A simple and sensitive spectrophotometric method is proposed for the determination of palladium (II) in ppm level using 4-amino-3-mercapto-6-methyl-1, 2, 4-tirazine (4-H)-5-one, a nitrogen, sulphur and oxygen donor triazine, as the spectrophotometric reagent. In aqueous medium at a pH of 11, Pd(II) forms a light yellow colored complex with the proposed spectrophotometric reagent. The optimum co...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1982
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.31.10_e305